Synthesis, crystal structure, spectra and magnetic properties of new manganese(III) and iron(III) dipicolinate complexes

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39896330" target="_blank" >RIV/00216275:25310/13:39896330 - isvavai.cz</a>

Result on the web

<a href="http://www.sciencedirect.com/science/article/pii/S0277538713002271" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0277538713002271</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.poly.2013.03.026" target="_blank" >10.1016/j.poly.2013.03.026</a>

Result language

angličtina

Original language name

Synthesis, crystal structure, spectra and magnetic properties of new manganese(III) and iron(III) dipicolinate complexes

Original language description

The four ionic manganese(III) and iron(III) dipicolinate complexes of formula (Hpia)[Fe-III(dipic)(2)]center dot 3H(2)O, (Hpia)[Mn-III(dipic)(2)]center dot(H(2)dipic)center dot 6H(2)O, (Hinia)]Fe-III(dipic)(2)]center dot 3H(2)O and (Hinia)[Mn-III(dipic)(2)]center dot 3H(2)O, where dipic(2-) = pyridine-2,6-dicarboxylate anion (dipicolinate anion), H(2)dipic = pyridine-2,6-dicarboxylic acid, Hpia(+) = 2-carboxamidepyridinium (picolinamidium) cation and Hinia(+) = 4-carboxamidepyridinium (isonicotinamidium) cation have been prepared and characterized by the single-crystal X-ray structure analysis. The SQUID-magnetic data were fitted to a zero-field splitting model revealing a slight magnetic anisotropy: vertical bar D vertical bar/hc similar to 3 cm(-1) for Mn(III).

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2013

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polyhedron

ISSN

0277-5387

e-ISSN

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Volume of the periodical

56

Issue of the periodical within the volume

June

Country of publishing house

GB - UNITED KINGDOM

Number of pages

9

Pages from-to

9-17

UT code for WoS article

000319958200002

EID of the result in the Scopus database

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