Hexacoordinate high-spin Fe(III) complexes composed of a pentadentate amino-type ligand and pseudohalido coligands

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F22%3A00563756" target="_blank" >RIV/68378271:_____/22:00563756 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15640/22:73618753
Result on the web
<a href="https://doi.org/10.1039/d2nj02294j" target="_blank" >https://doi.org/10.1039/d2nj02294j</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d2nj02294j" target="_blank" >10.1039/d2nj02294j</a>

Result language
angličtina
Original language name
Hexacoordinate high-spin Fe(III) complexes composed of a pentadentate amino-type ligand and pseudohalido coligands
Original language description
A new series of Fe(III) mononuclear complexes of the [Fe(Lam)(X)] type {where X = Cl (1), NCSe (2), NCS (3), N3 (4), and NCO (5)} have been prepared and characterized in detail. An untraditional pentadentate amino-ligand Lam was prepared by a reductive amination of an imino precursor Lim. The DC magnetic data confirm a high-spin state for 1–5 over the whole temperature scale, however, some significant differences in the magnetic data are observed. The spin Hamiltonian with the isotropic Zeeman term has been utilized for describing the zero-field splitting (ZFS) in 2, 3 and 5. In 1 and 4, the fo rmation of exchange coupled dimers is evident with the isotropic exchange coupling of antiferromagnetic nature. The zero-field splitting D parameters adopt small values: 1.15 (1), -0.74 (2), -1.7 (3), 1.5 (4) and -0.62 cm-1 (5) which match the theoretical predictions.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Project
<a href="/en/project/EF16_019%2F0000754" target="_blank" >EF16_019/0000754: Nanotechnologies for Future</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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