Isostructural crystals of bis(guanidinium) trioxofluoro-phosphate/phosphite in the ratio 1/0, 0.716/0.284, 0.501/0.499, 0.268/0.732, 0/1—crystal structures, vibrational spectra and second harmonic generation

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F22%3A00564664" target="_blank" >RIV/68378271:_____/22:00564664 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/22:10452472
Result on the web
<a href="https://hdl.handle.net/11104/0336314" target="_blank" >https://hdl.handle.net/11104/0336314</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3390/cryst12121694" target="_blank" >10.3390/cryst12121694</a>

Result language
angličtina
Original language name
Isostructural crystals of bis(guanidinium) trioxofluoro-phosphate/phosphite in the ratio 1/0, 0.716/0.284, 0.501/0.499, 0.268/0.732, 0/1—crystal structures, vibrational spectra and second harmonic generation
Original language description
The title structures of bis(guanidinium) trioxofluorophosphate, bis(guanidinium) trioxofluorophosphate-phosphite (0.716/0.284), bis(guanidinium) trioxofluorophosphate-phosphite (0.501/0.499), bis(guanidinium) trioxofluorophosphate-phosphite (0.268/0.732), and bis(guanidinium) phosphite are crystal-chemically isotypic. The P and O atoms of the substituted trioxofluorophosphate and phosphite anions share the same positions while the P-F and P-H hydrido are almost parallel and oriented in the same direction. Two symmetry-independent anions and two of three symmetry-independent cations are situated on the crystallographic mirror planes. The ions are interconnected by N-H O hydrogen bonds of moderate strength. The title crystals were also characterized by FTIR and FT Raman and the second harmonic generation (SHG). The relative SHG efficiency considerably decreases from bis(guanidinium) trioxofluorophosphate to bis(guanidinium) phosphite for the fundamental 1064 nm laser line.n
Czech name
—
Czech description
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Type
J<sub>SC</sub> - Article in a specialist periodical, which is included in the SCOPUS database
CEP classification
—
OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Project
<a href="/en/project/EF15_003%2F0000417" target="_blank" >EF15_003/0000417: Center for Advanced Materials: Design, Synthesis, and Applications</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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