(2-Azoniaethyl)guanidinium dichloride - A promising phase-matchable NLO material employing a simple hydrogen bond acceptor in its structure
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10296116" target="_blank" >RIV/00216208:11310/15:10296116 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11320/15:10296116
Result on the web
<a href="http://dx.doi.org/10.1016/j.optmat.2014.11.053" target="_blank" >http://dx.doi.org/10.1016/j.optmat.2014.11.053</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.optmat.2014.11.053" target="_blank" >10.1016/j.optmat.2014.11.053</a>
Alternative languages
Result language
angličtina
Original language name
(2-Azoniaethyl)guanidinium dichloride - A promising phase-matchable NLO material employing a simple hydrogen bond acceptor in its structure
Original language description
(2-Azoniaethyl)guanidinium dichloride (AEGCl), a salt of a functional guanidine derivative, was prepared and characterised by single-crystal and powder X-ray diffraction analysis, elemental analysis and by NMR, UV-Vis and vibrational spectroscopy. The crystal structure of AEGCl, which crystallises with the symmetry of the chiral space group P21, is built up via simple and multicentred N-H...Cl hydrogen bonds and further supported by C-H...Cl contacts. The compound is thermally robust and exhibits promising NLO properties with powder SHG efficiency better than potassium dihydrogen phosphate. In contrast, (2-azoniaethyl)guanidinium salts with inorganic oxoanions such as (2-azoniaethyl)guanidinium dinitrate and diperchlorate, synthesised for a comparison,form centrosymmetric crystal assemblies having several structurally independent ''molecules'' in their structures.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA14-05506S" target="_blank" >GA14-05506S: Crystal engineering of novel molecular crystals for non-linear optics</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Optical Materials
ISSN
0925-3467
e-ISSN
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Volume of the periodical
42
Issue of the periodical within the volume
Neuveden.
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
8
Pages from-to
39-46
UT code for WoS article
000351800300006
EID of the result in the Scopus database
2-s2.0-84924110332