A Cu(II) complex based on a Schiff base ligand derived from Ortho-vanillin: synthesis, DFT analysis and catalytic activities

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F23%3A00567419" target="_blank" >RIV/68378271:_____/23:00567419 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.molstruc.2022.134545" target="_blank" >https://doi.org/10.1016/j.molstruc.2022.134545</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2022.134545" target="_blank" >10.1016/j.molstruc.2022.134545</a>

Result language
angličtina
Original language name
A Cu(II) complex based on a Schiff base ligand derived from Ortho-vanillin: synthesis, DFT analysis and catalytic activities
Original language description
The synthesis of a new Cu(II) complex with a bidentate Schiff base is presented. The ligand L was characterized using 1H NMR, 13C NMR, IR and UV–Visible spectroscopy techniques. Structural analysis of CuL2 was carried out using single crystal X-ray diffraction in which the copper center adopts a square planar geometry with two naphthyl substituents perpendicular to the molecular plane. The structure has been further analyzed by IR and UV–Visible spectroscopy techniques. Density functional theory (DFT) and TD-DFT studies provided further information on the structural features and electronic tr ansitions of CuL2. The catalytic activity of CuL2 was investigated in the oxidation of selected primary and secondary alcohols.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Project
<a href="/en/project/EF16_019%2F0000760" target="_blank" >EF16_019/0000760: Solid State Physics for 21st century</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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