Design and manipulation of a minimalistic hydrocarbon nanocar on Au(111)
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F23%3A00574994" target="_blank" >RIV/68378271:_____/23:00574994 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1002/anie.202212395" target="_blank" >https://doi.org/10.1002/anie.202212395</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.202212395" target="_blank" >10.1002/anie.202212395</a>
Alternative languages
Result language
angličtina
Original language name
Design and manipulation of a minimalistic hydrocarbon nanocar on Au(111)
Original language description
Nanocars are carbon-based single-molecules with a precise design that facilitates their atomic-scale control on a surface. The rational design of these molecules is important in atomic and molecular-scale manipulation to advance the development of molecular machines, as well as for a better understanding of self assembly, diffusion and desorption processes. Here, we introduce the molecular design and construction of a collection of minimalistic nanocars. They feature an anthracene chassis and four benzene derivatives as wheels. After sublimation and adsorption on an Au(111) surface, we show controlled and fast manipulation of the nanocars along the surface using the tip of a scanning tunneling microscope (STM). The mechanism behin d the successful displacement is the induced dipole created over the nanocar by the STM tip. We utilized carbon monoxide functionalized tips both to avoid decomposi tion and accidentally picking the nanocars up during the manipulation. This strategy allowed thousands of ma neuvers to successfully win the Nanocar Race II championship.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Angewandte Chemie - International Edition
ISSN
1433-7851
e-ISSN
1521-3773
Volume of the periodical
62
Issue of the periodical within the volume
6
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
e202212395
UT code for WoS article
000898389500001
EID of the result in the Scopus database
2-s2.0-85143890734