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Synergetic radical-scavenging effect in the complex of copper(II) with the thiosemicarbazone of salicylaldehyde

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F23%3A00579599" target="_blank" >RIV/68378271:_____/23:00579599 - isvavai.cz</a>

  • Result on the web

    <a href="https://doi.org/10.1080/00958972.2023.2261603" target="_blank" >https://doi.org/10.1080/00958972.2023.2261603</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1080/00958972.2023.2261603" target="_blank" >10.1080/00958972.2023.2261603</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synergetic radical-scavenging effect in the complex of copper(II) with the thiosemicarbazone of salicylaldehyde

  • Original language description

    The radical scavenging activities of salicylaldehyde thiosemicarbazone and its copper(II) and cadmium(II) complexes were evaluated by in vitro experiments in the reaction with 2,2'-diphenyl-1-picrylhydrazyl. Salicylic aldehyde thiosemicarbazone complex with Cu(II) shows significantly higher radical-scavenging activity than Cu2+ ions, salicylaldehyde thiosemicarbazone, and Cd(II) complex. Electrochemical, EPR and kinetic studies revealed that the high rate of reaction and efficiency is due to the mechanism of electron transfer, which is enhanced by the synergetic effect of the ligand structure and the ability of the copper ion to exhibit variable valencies.n

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

    <a href="/en/project/EF16_019%2F0000760" target="_blank" >EF16_019/0000760: Solid State Physics for 21st century</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Coordination Chemistry

  • ISSN

    0095-8972

  • e-ISSN

    1029-0389

  • Volume of the periodical

    76

  • Issue of the periodical within the volume

    13-15

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    13

  • Pages from-to

    1763-1775

  • UT code for WoS article

    001076486500001

  • EID of the result in the Scopus database

    2-s2.0-85173084538