Highly selective on-surface ring-opening of aromatic azulene moiety
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F24%3A00584954" target="_blank" >RIV/68378271:_____/24:00584954 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15640/24:73624753
Result on the web
<a href="https://doi.org/10.1021/jacs.3c11652" target="_blank" >https://doi.org/10.1021/jacs.3c11652</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jacs.3c11652" target="_blank" >10.1021/jacs.3c11652</a>
Alternative languages
Result language
angličtina
Original language name
Highly selective on-surface ring-opening of aromatic azulene moiety
Original language description
Controllable ring-opening of polycyclic aromatic hydrocarbons plays a crucial role in various chemical and biological processes. However, breaking down aromatic covalent C–C bonds is exceptionally challenging due to their high stability and strong aromaticity. This study presents a seminal report on the precise and highly selective on-surface ring-opening of the seven-membered ring within the aromatic azulene moieties under mild conditions. The chemical structures of the resulting products were identified using bond-resolved scanning probe microscopy. Furthermore, through density functional theory calculations, we uncovered the mechanism behind the ring-opening process and elucidated its chemical driving force.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/GX20-13692X" target="_blank" >GX20-13692X: 1D molecular chains on surfaces</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of the American Chemical Society
ISSN
0002-7863
e-ISSN
1520-5126
Volume of the periodical
146
Issue of the periodical within the volume
2
Country of publishing house
US - UNITED STATES
Number of pages
9
Pages from-to
1563-1571
UT code for WoS article
001144606800001
EID of the result in the Scopus database
2-s2.0-85181566151