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Thick does the trick: genesis of ferroelectricity in 2D GeTe-rich (GeTe)m(Sb2Te3)n lamellae

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F24%3A00585018" target="_blank" >RIV/68378271:_____/24:00585018 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11320/23:10471573 RIV/00216224:14310/24:00135375

  • Result on the web

    <a href="https://hdl.handle.net/11104/0352787" target="_blank" >https://hdl.handle.net/11104/0352787</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/advs.202304785" target="_blank" >10.1002/advs.202304785</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Thick does the trick: genesis of ferroelectricity in 2D GeTe-rich (GeTe)m(Sb2Te3)n lamellae

  • Original language description

    The possibility to engineer (GeTe)m(Sb2Te3)n phase-change materials to co-host ferroelectricity is extremely attractive. The combination of these functionalities holds great technological impact, potentially enabling the design of novel multifunctional devices. Here an experimental and theoretical study of epitaxial (GeTe)m(Sb2Te3)n with GeTe-rich composition is presented. These layered films feature a tunable distribution of (GeTe)m(Sb2Te3)1 blocks of different sizes. Breakthrough evidence of ferroelectric displacement in thick (GeTe)m(Sb2Te3)1 lamellae is provided. The density functional theory calculations suggest the formation of a tilted (GeTe)m slab sandwiched in GeTe-rich blocks. That is, the net ferroelectric polarization is confined almost in-plane, representing an unprecedented case between 2D and bulk ferroelectric materials. The ferroelectric behavior is confirmed by piezoresponse force microscopy and electroresistive measurements.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    <a href="/en/project/GM22-22000M" target="_blank" >GM22-22000M: Multipole antiferromagnets: New interlinked chapters in crystallography, band structure, and electronics</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2024

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Advanced Science

  • ISSN

    2198-3844

  • e-ISSN

    2198-3844

  • Volume of the periodical

    11

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    11

  • Pages from-to

    2304785

  • UT code for WoS article

    001108011600001

  • EID of the result in the Scopus database

    2-s2.0-85177180181