Heteroleptic Ni(II) complexes containing chelating benzoato ligand with sharp bite angle: syntheses, crystal structures, and magnetism
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F24%3A00588401" target="_blank" >RIV/68378271:_____/24:00588401 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.ica.2024.122178" target="_blank" >https://doi.org/10.1016/j.ica.2024.122178</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ica.2024.122178" target="_blank" >10.1016/j.ica.2024.122178</a>
Alternative languages
Result language
angličtina
Original language name
Heteroleptic Ni(II) complexes containing chelating benzoato ligand with sharp bite angle: syntheses, crystal structures, and magnetism
Original language description
From the system Ni(OH)2 – 4,4′-dmbpy – HBz (HBz = benzoic acid, 4,4′-dmbpy = 4,4′-dimethyl-2,2′-bipyridine) under various experimental conditions three complexes were isolated, namely light blue [Ni(4,4′-dmbpy)(Bz)2(H2O)] (1), violet [Ni(4,4′-dmbpy)2(Bz)](Bz)⋅2HBz (2), and pink microcrystalline product [Ni(4,4′-dmbpy)3](Bz)2⋅3.5H2O (3). The crystal structures of 1 and 2 were determined. The crystal structure of 1 is formed of neutral molecules, in which the Ni(II) central atom is hexa-coordinated by one chelating diamine ligand, one chelating and one monodentate benzoato ligands, and one aqua ligand. The crystal structure of 2 is ionic and in the complex cation the Ni(II) atom is hexa-coordinated by two chelating diamine ligands and one chelating benzoato ligand. The obtained experimental results were supported by ab initio and DFT calculations.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganica chimica acta
ISSN
0020-1693
e-ISSN
1873-3255
Volume of the periodical
571
Issue of the periodical within the volume
Oct
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
10
Pages from-to
122178
UT code for WoS article
001339610800001
EID of the result in the Scopus database
2-s2.0-85196423375