Study of the theoretical and experimental paths for condensation between a triamine and 2-hydroxybenzaldehyde in the presence of the Ni(II) ion, supported by spectral, structural, DFT and docking studies

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F25%3A00601799" target="_blank" >RIV/68378271:_____/25:00601799 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.molstruc.2024.140403" target="_blank" >https://doi.org/10.1016/j.molstruc.2024.140403</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2024.140403" target="_blank" >10.1016/j.molstruc.2024.140403</a>

Result language
angličtina
Original language name
Study of the theoretical and experimental paths for condensation between a triamine and 2-hydroxybenzaldehyde in the presence of the Ni(II) ion, supported by spectral, structural, DFT and docking studies
Original language description
In this work, all possible products in the reaction between N1-(2-amino-ethyl)-propane-1,3-diamine and 2-hydroxybenzaldehyde in the absence and presence of the nickel(II) ion, as a collector of the reagents, were studied by the theoretical and experimental methods. In continue, synthesis, characterization and coordination chemistry of two new chiral/racemic complexes of nickel(II), racemic-RS-[Ni(L)]NO3 (1) and [Ni(L)]SCN (2), HL: 2-(((2-((3-aminopropyl)amino)ethyl)imino)methyl)phenol, obtained from a template reaction were discussed. The two complexes were identified by elemental analysis, FT-IR spectroscopy and single-crystal X-ray diffraction.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Project
<a href="/en/project/LM2023051" target="_blank" >LM2023051: Research infrastructure CzechNanoLab</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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