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Doubts about the popular Kissinger method of kinetic evaluation and its applicability for crystallization of cooling melts requiring equilibrium temperatures

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21110%2F20%3A00339304" target="_blank" >RIV/68407700:21110/20:00339304 - isvavai.cz</a>

  • Result on the web

    <a href="https://doi.org/10.1007/s10973-020-09430-3" target="_blank" >https://doi.org/10.1007/s10973-020-09430-3</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s10973-020-09430-3" target="_blank" >10.1007/s10973-020-09430-3</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Doubts about the popular Kissinger method of kinetic evaluation and its applicability for crystallization of cooling melts requiring equilibrium temperatures

  • Original language description

    The famous Kissinger’s kinetic evaluation method (Anal Chem 29:1702, 1957) is examined with respect to the feasible impact of the individual quantities and assumptions involved. It is accentuated that the missing term on heat inertia may change the resulting values when searching for activation energies. Particular attention is paid to the heating rate, β, particularly when applied under opposite process of cooling. In such case of melt solidification, an additional thermodynamic term for the melt undercooling is needed to be incorporated which provides an alternative form of evaluation. Despite as many as 8000 applications caused by the obvious methods simplicity, these affects was overlooked. It is surprising that anybody who evolved various alternatives of the Kissinger method did not find any reasons for its criticism.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20101 - Civil engineering

Result continuities

  • Project

    <a href="/en/project/FV40007" target="_blank" >FV40007: Innovation of the production technology of lightened brick body for thin-walled brick blocks</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Thermal Analysis and Calorimetry

  • ISSN

    1388-6150

  • e-ISSN

    1588-2926

  • Volume of the periodical

    142

  • Issue of the periodical within the volume

    5

  • Country of publishing house

    HU - HUNGARY

  • Number of pages

    4

  • Pages from-to

    2095-2098

  • UT code for WoS article

    000516229900005

  • EID of the result in the Scopus database

    2-s2.0-85079629650