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Deconvolution of DSC peaks of high-temperature phases in an illite/smectite-CaCO3mixture

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21110%2F23%3A00373877" target="_blank" >RIV/68407700:21110/23:00373877 - isvavai.cz</a>

  • Result on the web

    <a href="https://doi.org/10.1088/1742-6596/2628/1/012021" target="_blank" >https://doi.org/10.1088/1742-6596/2628/1/012021</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1088/1742-6596/2628/1/012021" target="_blank" >10.1088/1742-6596/2628/1/012021</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Deconvolution of DSC peaks of high-temperature phases in an illite/smectite-CaCO3mixture

  • Original language description

    Heat flow curves measured in differential scanning calorimetry (DSC) may contain overlapping peaks corresponding to multiple-step processes. To analyze the individual steps in such a process, a deconvolution of the overlapping peaks into the individual peaks is necessary. Using the Frazer-Suzuki function to describe asymmetric peaks, we apply a nonlinear least squares analysis to perform the decomposition of heat flow curves measured for a mixture of an illite/smectite clay with 19.6 wt.% of CaCO3. The curves contain two overlapping peaks associated with the crystallizations of gehlenite and anorthite in the temperature interval from 900 °C to 1050 °C. Several versions of the decomposition analysis may be used, depending on the number of optimized parameters. These may range from four to all eight parameters (four for either peak). We applied the versions with seven and eight fitting parameters, yielding results that are in very good agreement with the experimental data.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

  • OECD FORD branch

    20501 - Materials engineering

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Journal of Physics: Conference Series 2628 (2023)

  • ISBN

  • ISSN

    1742-6588

  • e-ISSN

    1742-6596

  • Number of pages

    8

  • Pages from-to

  • Publisher name

    IOP Publishing Ltd.

  • Place of publication

    Bristol

  • Event location

    Poprad

  • Event date

    Sep 6, 2023

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article