Luminescent and sustainable d10 coinage metal thiolate coordination polymers for high- temperature optical sensing
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21670%2F23%3A00363308" target="_blank" >RIV/68407700:21670/23:00363308 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.isci.2023.106016" target="_blank" >https://doi.org/10.1016/j.isci.2023.106016</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.isci.2023.106016" target="_blank" >10.1016/j.isci.2023.106016</a>
Alternative languages
Result language
angličtina
Original language name
Luminescent and sustainable d10 coinage metal thiolate coordination polymers for high- temperature optical sensing
Original language description
The d10 coinage metal coordination polymers (CPs) are known to display photophysical properties which can be tuned depending on the functionality of the ligand. Three new CPs made of d10 coinage metals and methyl thiosalicylate, [M(o-SPhCO2Me)]n (M = Cu, Ag, Au), are reported. They are all constructed from one-dimensional metal-sulfur networks, in which Cu and Ag are three-coordinated to sulfur atoms, whereas Au is only two-coordinated. It results that both Cu(I) and Ag(I) CPs show orange photoemission at room temperature, and the Au(I) one exhibits near-infrared emission at low temperatures. The intense orange-emissive Ag(I) CP and the blue-emissive coumarin 120 have been mixed in an organic matrix, the polyvinylidene fluoride (PVDF), to form a dual luminescent flexible composite film. This film, evaluated for thermometry, shows great sensitivity for temperatures up to 100C, a temperature never reached with non-lanthanide-based CPs.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10400 - Chemical sciences
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
iScience
ISSN
2589-0042
e-ISSN
2589-0042
Volume of the periodical
2023
Issue of the periodical within the volume
26(2)
Country of publishing house
GB - UNITED KINGDOM
Number of pages
12
Pages from-to
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UT code for WoS article
000990665500001
EID of the result in the Scopus database
2-s2.0-85147439540