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Luminescent and sustainable d10 coinage metal thiolate coordination polymers for high- temperature optical sensing

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21670%2F23%3A00363308" target="_blank" >RIV/68407700:21670/23:00363308 - isvavai.cz</a>

  • Result on the web

    <a href="https://doi.org/10.1016/j.isci.2023.106016" target="_blank" >https://doi.org/10.1016/j.isci.2023.106016</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.isci.2023.106016" target="_blank" >10.1016/j.isci.2023.106016</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Luminescent and sustainable d10 coinage metal thiolate coordination polymers for high- temperature optical sensing

  • Original language description

    The d10 coinage metal coordination polymers (CPs) are known to display photophysical properties which can be tuned depending on the functionality of the ligand. Three new CPs made of d10 coinage metals and methyl thiosalicylate, [M(o-SPhCO2Me)]n (M = Cu, Ag, Au), are reported. They are all constructed from one-dimensional metal-sulfur networks, in which Cu and Ag are three-coordinated to sulfur atoms, whereas Au is only two-coordinated. It results that both Cu(I) and Ag(I) CPs show orange photoemission at room temperature, and the Au(I) one exhibits near-infrared emission at low temperatures. The intense orange-emissive Ag(I) CP and the blue-emissive coumarin 120 have been mixed in an organic matrix, the polyvinylidene fluoride (PVDF), to form a dual luminescent flexible composite film. This film, evaluated for thermometry, shows great sensitivity for temperatures up to 100C, a temperature never reached with non-lanthanide-based CPs.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10400 - Chemical sciences

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    iScience

  • ISSN

    2589-0042

  • e-ISSN

    2589-0042

  • Volume of the periodical

    2023

  • Issue of the periodical within the volume

    26(2)

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    12

  • Pages from-to

  • UT code for WoS article

    000990665500001

  • EID of the result in the Scopus database

    2-s2.0-85147439540