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Intercalated Clays - Precursors for Polymer-Clay Nanocomposites

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28110%2F03%3A63501159" target="_blank" >RIV/70883521:28110/03:63501159 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Intercalated Clays - Precursors for Polymer-Clay Nanocomposites

  • Original language description

    Molecular modeling revealed the interlayer structure and differences in intercalation behaviour of Cetylpyridinium (CP) and Cetyltrimethylammonium (CTA) cations montmorillonite. CTA-montmorillonite exhibits significantly higher total sublimation energy and higher host-guest interaction energy than the CP-montmorillonite. The main difference between both intercalates is in charge distribution on the host layers and guest species, The charge transfer from the guest species to the host layer is higher in CTA-montmorillonite, than in CP-montmorillonites, and consequently the charge polarisation between the host and guest layers is much higher in CTA-montmorillonite. This leads to much stronger host-guest electrostatic interaction in case of CTA-montmorillonite. Results are established as a basic data for polymer/clay nanocomposite systems.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CD - Macromolecular chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA106%2F02%2F0205" target="_blank" >GA106/02/0205: Creation of controlled structures of polymer systém with help of intercalates nanofiller</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2003

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    PPS-19 Melbourne

  • ISBN

  • ISSN

  • e-ISSN

  • Number of pages

    4

  • Pages from-to

  • Publisher name

    Polymer Processing Society

  • Place of publication

    Melbourne, Austrálie

  • Event location

    Melbourne, Astrálie

  • Event date

    Jul 7, 2003

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article