Intercalated Clays - Precursors for Polymer-Clay Nanocomposites
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28110%2F03%3A63501159" target="_blank" >RIV/70883521:28110/03:63501159 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Intercalated Clays - Precursors for Polymer-Clay Nanocomposites
Original language description
Molecular modeling revealed the interlayer structure and differences in intercalation behaviour of Cetylpyridinium (CP) and Cetyltrimethylammonium (CTA) cations montmorillonite. CTA-montmorillonite exhibits significantly higher total sublimation energy and higher host-guest interaction energy than the CP-montmorillonite. The main difference between both intercalates is in charge distribution on the host layers and guest species, The charge transfer from the guest species to the host layer is higher in CTA-montmorillonite, than in CP-montmorillonites, and consequently the charge polarisation between the host and guest layers is much higher in CTA-montmorillonite. This leads to much stronger host-guest electrostatic interaction in case of CTA-montmorillonite. Results are established as a basic data for polymer/clay nanocomposite systems.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA106%2F02%2F0205" target="_blank" >GA106/02/0205: Creation of controlled structures of polymer systém with help of intercalates nanofiller</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
PPS-19 Melbourne
ISBN
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ISSN
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e-ISSN
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Number of pages
4
Pages from-to
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Publisher name
Polymer Processing Society
Place of publication
Melbourne, Austrálie
Event location
Melbourne, Astrálie
Event date
Jul 7, 2003
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
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