Cubane Arrives on the Cucurbituril Scene

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28110%2F17%3A63516600" target="_blank" >RIV/70883521:28110/17:63516600 - isvavai.cz</a>
Alternative codes found
RIV/00216224:14310/17:00111640
Result on the web
<a href="http://pubs.acs.org/doi/abs/10.1021/acs.orglett.7b01029" target="_blank" >http://pubs.acs.org/doi/abs/10.1021/acs.orglett.7b01029</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.orglett.7b01029" target="_blank" >10.1021/acs.orglett.7b01029</a>

Result language
angličtina
Original language name
Cubane Arrives on the Cucurbituril Scene
Original language description
Cubane, an intriguing chemical curiosity first studied in the early 1960s, has become a valuable structural motif and has recently been involved in the structures of a great number of prospective compounds. The first dicationic supramolecular guest 5 is prepared and derived from a 1,4-disubstituted cubane moiety, and its binding behavior toward cucurbit[n]urils (CBn) and cyclodextrins (CD) is studied. The bisimidazolium salt 5 forms 1:1 inclusion complexes with CB7, CB8, and β-CD with the respective association constants (6.7 ± 0.5) × 1011 M-1, (1.5 ± 0.2) × 109 M-1, and <102 M-1 in water. The solid-state structures of the 5@CB7 and 5@CB8 complexes are also reported.
Czech name
—
Czech description
—

Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry

Project
<a href="/en/project/LM2015043" target="_blank" >LM2015043: Czech Infrastructure for Integrative Structural Biology</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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