Catalytic oxidation using nitrous oxide

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28140%2F17%3A63516780" target="_blank" >RIV/70883521:28140/17:63516780 - isvavai.cz</a>

Result on the web

<a href="https://www.matec-conferences.org/articles/matecconf/pdf/2017/39/matecconf_cscc2017_02053.pdf" target="_blank" >https://www.matec-conferences.org/articles/matecconf/pdf/2017/39/matecconf_cscc2017_02053.pdf</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1051/matecconf/201712502053" target="_blank" >10.1051/matecconf/201712502053</a>

Result language

angličtina

Original language name

Catalytic oxidation using nitrous oxide

Original language description

Nitrous oxide is a very inert gas used generally as oxidant as it offers some advantage compared with other oxidants such as O2 but a considerably higher temperature (&gt; 526 °C) is often required. For particular cases such as the oxidation of sugar alcohols, especially for the oxidation of primary alcohols to aldehydes, N2O has the advantage over O2 of a higher reaction selectivity. In the present paper we present the modelling of oxidation reaction of sugar alcohols using an oxidizing agent in low concentrations, which is important to suppress subsequent oxidation reactions due to the very low residual concentrations of the oxidizing agent. For orientation experiments we chose nitrous oxide generated by thermal decomposition of ammonium nitrate. Kinetic modeling of the reaction was performed after determination of the differential equations that describe the system under study.

Czech name

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Czech description

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Type

D - Article in proceedings

CEP classification

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OECD FORD branch

20401 - Chemical engineering (plants, products)

Project

<a href="/en/project/LO1303" target="_blank" >LO1303: Promoting sustainability and development of the Centre for Security, Information and Advanced Technologies (CEBIA-Tech)</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2017

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Article name in the collection

MATEC Web of Conferences

ISBN

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ISSN

2261-236X

e-ISSN

neuvedeno

Number of pages

4

Pages from-to

"nestrankovano"

Publisher name

EDP Sciences

Place of publication

Les Ulis

Event location

Heraklion, Crete

Event date

Jul 14, 2017

Type of event by nationality

WRD - Celosvětová akce

UT code for WoS article

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