Adamantane-bearing benzylamines and benzylamides: Novel building blocks for supramolecular systems with finely tuned binding properties towards ?-cyclodextrin
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28610%2F13%3A43869675" target="_blank" >RIV/70883521:28610/13:43869675 - isvavai.cz</a>
Alternative codes found
RIV/68081715:_____/13:00393311 RIV/70883521:28110/13:43869675
Result on the web
<a href="http://dx.doi.org/10.1080/10610278.2013.783916" target="_blank" >http://dx.doi.org/10.1080/10610278.2013.783916</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/10610278.2013.783916" target="_blank" >10.1080/10610278.2013.783916</a>
Alternative languages
Result language
angličtina
Original language name
Adamantane-bearing benzylamines and benzylamides: Novel building blocks for supramolecular systems with finely tuned binding properties towards ?-cyclodextrin
Original language description
Novel building blocks for the synthesis of supramolecular components based on adamantane-bearing benzylamines were prepared. The binding properties of these amines and the corresponding acetamides towards ?-cyclodextrin (?-CD) were studied using mass spectrometry, NMR spectrometry, isothermal titration calorimetry and semi-empirical calculations. It was found that all of the examined guests predominantly formed 1:1 inclusion complexes in an enthalpy-driven manner with association constants of the orderof 10 2-103 M-1. Stronger binding to the ?-CD cavity was observed for guests with a longer spacer between the adamantane and benzene moieties and/or a 1,4-disubstituted benzene ring.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Supramolecular Chemistry
ISSN
1061-0278
e-ISSN
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Volume of the periodical
25
Issue of the periodical within the volume
6
Country of publishing house
GB - UNITED KINGDOM
Number of pages
13
Pages from-to
349-361
UT code for WoS article
000320020400005
EID of the result in the Scopus database
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