Vanadium metal-organic frameworks derived VOx/Carbon nano-sheets and paperclip-like VOx/nitrogen-doped carbon nanocomposites for sodium-ion battery electrodes

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28610%2F22%3A63548639" target="_blank" >RIV/70883521:28610/22:63548639 - isvavai.cz</a>

Alternative codes found

RIV/00216305:26220/22:PU144206 RIV/00216224:14740/22:00127888

Result on the web

<a href="https://www.sciencedirect.com/science/article/pii/S0254058421013675" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0254058421013675</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.matchemphys.2021.125584" target="_blank" >10.1016/j.matchemphys.2021.125584</a>

Result language

angličtina

Original language name

Vanadium metal-organic frameworks derived VOx/Carbon nano-sheets and paperclip-like VOx/nitrogen-doped carbon nanocomposites for sodium-ion battery electrodes

Original language description

In this work, vanadium metal-organic framework derived VOx/carbon and VOx/N-doped carbon nanocomposites are presented. The methodology introduced here is based on a novel polyol synthesis of vanadium metal-organic frameworks (MOFs) involving a microwave-assisted solvothermal reaction of vanadyl acetylacetonate with biphenyl-4,4′-dicarboxylic acid (Bpdc) and/or 2,2′-bipyridine-4,4′-dicarboxylic acid (NBpdc) in diethylene glycol (DEG) at the temperature of 230 °C. The V-based MOFs, labeled as V-Bpdc and V-NBpdc, were used as precursors for the preparation of VOx/carbon and VOx/N-doped carbon nanocomposites with unique sponge-like nano-sheet and paperclip-like morphology, respectively. The nanocomposites were obtained via thermal transformation of as-prepared vanadium MOFs in the argon atmosphere at 600 °C. The VOx/carbon sample consists of nano-sheets with the thickness 5–20 nm while the VOx/N-doped carbon paperclip-like nanocomposite has a rod diameter 35–70 nm. It was found that the approach reported here provides an effective and simple preparation pathway of carbon-based nanocomposites containing homogeneously distributed VOx species. Both V-MOFs and V-MOF-derived nanocomposites were characterized by the variety of physicochemical methods. In the following step, the obtained nanocomposites were investigated as electrode materials in sodium-ion batteries. Based on the obtained results, high electrochemical activities of VOx/carbon and VOx/N-doped carbon nanocomposites were evidenced. Particularly, in the case of VOx/N-doped carbon-based electrode, high capacity and low irreversible capacity were achieved. Therefore, reported materials are found to be promising candidates for electrode materials in sodium-ion batteries.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

21001 - Nano-materials (production and properties)

Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2022

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Materials Chemistry and Physics

ISSN

0254-0584

e-ISSN

—

Volume of the periodical

278

Issue of the periodical within the volume

Neuveden

Country of publishing house

CH - SWITZERLAND

Number of pages

17

Pages from-to

nestrankovano

UT code for WoS article

000764174500004

EID of the result in the Scopus database

2-s2.0-85121370255