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Activation of NdFeB magnetic material upon exposure to oxygen plasma

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28610%2F25%3A63595763" target="_blank" >RIV/70883521:28610/25:63595763 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S0169433225020550" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0169433225020550</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.apsusc.2025.164339" target="_blank" >10.1016/j.apsusc.2025.164339</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Activation of NdFeB magnetic material upon exposure to oxygen plasma

  • Original language description

    In bonded NdFeB magnets, the fillers’ adhesion in the polymer matrix of composites is often insufficient, necessitating filler wettability modification before mixing with liquid polymers. Inductively coupled radiofrequency oxygen plasma was used to modify the surface wettability of commercial NdFeB flakes. A pronounced minimum in water contact angle (WCA) was observed after approximately 100 ms of treatment in plasma (50 Pa, 500 W). A deeper minimum was observed upon treatment in the flowing afterglow. The flux of oxygen atoms on the NdFeB flakes’ surface was ∼3 × 1023 m−2 s−1, and the WCA below 20° was observed after treating the samples in the afterglow for 0.05–0.5 s; corresponding O-atom doses 1022–1023 m−2. Larger doses caused a gradual loss of hydrophilicity, and an initial WCA of ∼75° was established after treating the samples in the afterglow for ∼40 s. This was attributed to the segregation and oxidation of iron on the NdFeB surface. Thorough XPS depth profiling revealed oxidation kinetics. The treatment in the glowing plasma caused a similar evolution, except that hydrophobicity was re-established after 1-s plasma treatment. The segregation of iron on the surface caused the formation of Fe2O3, and the intermediate layer toward the bulk consisted of Nd2O3 dispersed in the Fe matrix.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>SC</sub> - Article in a specialist periodical, which is included in the SCOPUS database

  • CEP classification

  • OECD FORD branch

    10305 - Fluids and plasma physics (including surface physics)

Result continuities

  • Project

  • Continuities

    V - Vyzkumna aktivita podporovana z jinych verejnych zdroju

Others

  • Publication year

    2025

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Applied Surface Science

  • ISSN

    0169-4332

  • e-ISSN

  • Volume of the periodical

    713

  • Issue of the periodical within the volume

    Neuveden

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    12

  • Pages from-to

    nestránkováno

  • UT code for WoS article

    001694847100001

  • EID of the result in the Scopus database

    2-s2.0-105013657020