Complexation of Europium(III) by Bis(dialkyltriazinyl)bipyridines in 1-Octanol

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10123415" target="_blank" >RIV/00216208:11310/12:10123415 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1021/ic202119x" target="_blank" >http://dx.doi.org/10.1021/ic202119x</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/ic202119x" target="_blank" >10.1021/ic202119x</a>

Result language

angličtina

Original language name

Complexation of Europium(III) by Bis(dialkyltriazinyl)bipyridines in 1-Octanol

Original language description

The present work focuses on highly selective ligands for An(III)/Ln(III) separation: bis(triazinyl)bipyriclines (BTBPs). By combining time-resolved laser-induced fluorescence spectroscopy, nanoelectrospray ionization mass spectrometry, vibronic sidebandspectroscopy, and X-ray diffraction, we obtain a detailed picture of the structure and stoichiometry of the first coordination sphere of Eu(III)-BTBP complexes in an octanolic solution. The main focus is on the 1:2 complexes because extraction studies revealed that those are the species extracted into the organic phase. The investigations on europium(III) complexes of BTBP with different triazin alkylation revealed differences in the formed complexes due to the bulkiness of the ligands. Because of the vibronic sidebands in the fluorescence spectra, we were able to detect whether or not nitrate ligands are coordinated in the first coordination sphere of the Eu-BTBP complexes. In solution, less sterically demanding BTBP offers enough spac

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2012

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Inorganic Chemistry

ISSN

0020-1669

e-ISSN

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Volume of the periodical

51

Issue of the periodical within the volume

1

Country of publishing house

US - UNITED STATES

Number of pages

10

Pages from-to

591-600

UT code for WoS article

000298712000075

EID of the result in the Scopus database

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