Highly enantioselective organocatalytic alpha-selenylation of aldehydes using hypervalent iodine compounds

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F13%3A10159270" target="_blank" >RIV/00216208:11310/13:10159270 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.tetasy.2013.02.008" target="_blank" >http://dx.doi.org/10.1016/j.tetasy.2013.02.008</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.tetasy.2013.02.008" target="_blank" >10.1016/j.tetasy.2013.02.008</a>

Result language
angličtina
Original language name
Highly enantioselective organocatalytic alpha-selenylation of aldehydes using hypervalent iodine compounds
Original language description
The highly enantioselective organocatalytic alpha-selenylation reaction of aldehydes using a hypervalent iodine compound as an oxidative agent from commercially available phenyl diselenide under mild oxidative conditions is described. This transformationaffords alpha-selenyl aldehydes in good yields and with excellent enantioselectivities. By using hypervalent iodine compounds, it opens up a suitable and alternative way for the preparation of biologically active building blocks such as beta-hydroxy alcohols, alpha-amino acids, and alpha-hydroxy esters.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
<a href="/en/project/GAP207%2F10%2F0428" target="_blank" >GAP207/10/0428: Enantioselective organocatalytic alpha-alkynylation,alkenylation and arylation of aldehydes and ketones</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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