Reactivity Studies on an Intramolecularly Coordinated Organotin(IV) Carbonate

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F14%3A10271764" target="_blank" >RIV/00216208:11310/14:10271764 - isvavai.cz</a>
Alternative codes found
RIV/00216275:25310/14:39898817
Result on the web
<a href="http://dx.doi.org/10.1021/om5002759" target="_blank" >http://dx.doi.org/10.1021/om5002759</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om5002759" target="_blank" >10.1021/om5002759</a>

Result language
angličtina
Original language name
Reactivity Studies on an Intramolecularly Coordinated Organotin(IV) Carbonate
Original language description
The reactivity of the intramolecularly coordinated organotin(IV) carbonate L(Ph)Sn(CO3) (1), where L stands for an N,C,N-chelating ligand, 2,6-(Me2NCH2)(2)C6H3, was studied. The treatment of 1 with ferrocene-based carboxylic acids RCOOH afforded the organotin(IV) dicarboxylates LPhSn(O2CR)(2), where R is ferrocenyl (2), 2-ferrocenylethyl (3), and [(1E)-2-ferrocenyl] ethenyl (4). Surprisingly, compounds 2-4 are sensitive to moisture and easily hydrolyze with condensation into the corresponding hexamericorganotin oxo clusters (PhSnO)(6)(O2CR)(6) (R = ferrocenyl (5), 2-ferrocenylethyl (6), and [(1E)-2-ferrocenyl]ethenyl (7)) possessing a Sn6O6 drumlike core. On the other hand, treatment of 1 with non-carboxylic acids such as HOTf, H3BO3, H3PO3, and t-BuPO3H2 afforded the triflate salt of a cationic organotin(IV) hydroxide {[LPh(H2O)Sn(mu-OH)](2)}(OTf)(2) (8), stannaboroxine LPhSnB2O3(OH)(2) (9), and organotin(IV) phosphite [L(Ph)Sn(HPO3)](2) (10) and phosphonate {[L(Ph)Sn](2)(mu-OH2)(mu-
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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