Intramolecularly Coordinated Group 14 and 15 Chalcogenites
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39896783" target="_blank" >RIV/00216275:25310/13:39896783 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/om3009553" target="_blank" >http://dx.doi.org/10.1021/om3009553</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om3009553" target="_blank" >10.1021/om3009553</a>
Alternative languages
Result language
angličtina
Original language name
Intramolecularly Coordinated Group 14 and 15 Chalcogenites
Original language description
The synthesis of N -} M intramolecularly coordinated group 14 and 15 chalcogenites is reported. The N -} Sn intramolecularly coordinated organotin(IV) carbonate L(Ph)SnCO3 (1), where L is the N,C,N-chelating ligand 2,6-(Me2NCH2)(2)C6H3-, reacts with SO2and SeO2 to provide the organotin(IV) sulfite L(Ph)SnSO3 (4) and selenite [L(Ph)SnSeO3](2) (5), respectively. Treatment of [LSbO](2) (2) and [LBiO](2) (3) with SeO2 provided the organoantimony and bismuth selenites LSbSeO3 (6) and [LBiSeO3](3) (7), respectively. Compounds 5-7 are rare examples of mixed element oxides with well-defined stoichiometry MSeO3 (M = Sn, Sb, Bi). Compounds 4-7 were characterized by means of elemental analyses, H-1, C-13, Se-77, and Sn-119 NMR spectroscopies, IR spectroscopy, and single-crystal X-ray diffraction analysis.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP106%2F10%2F0443" target="_blank" >GAP106/10/0443: Organometallic chalcogenides of 14 and 15 group as nanodimensional and MOCVD materials</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
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Volume of the periodical
32
Issue of the periodical within the volume
1
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
157-163
UT code for WoS article
000313606200019
EID of the result in the Scopus database
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