Complexing properties of 2-pyridylphoshonate and 2-pyridylsulfonate ligands for Zn2+ and Ag+ central atoms
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F22%3A10454357" target="_blank" >RIV/00216208:11310/22:10454357 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=xWhKtRVQvo" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=xWhKtRVQvo</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/00958972.2022.2127095" target="_blank" >10.1080/00958972.2022.2127095</a>
Alternative languages
Result language
angličtina
Original language name
Complexing properties of 2-pyridylphoshonate and 2-pyridylsulfonate ligands for Zn2+ and Ag+ central atoms
Original language description
The Zn(2+)/Ag(+)-pypo and pysu (pypo = 2-pyridylphosphonate, pysu = 2-pyridylsulfonate) complexes speciation in aqueous solution at I = 0.1 M (KNO3) and 25 °C is described in detail under our experimental synthetic conditions. Protonation and stability constants were determined, and distribution diagrams show protonated and deprotonated complexes formation in the case of Zn(2+)/Ag(+) pypo/pysu binary system, respectively. Moreover, the new complex, {[Zn(H(2)pypo)(2)(H2O)(2)]}(n)(ClO4)(2n) . 2n H2O, was isolated and its spectral and structural properties were determined. An unusual pypo bidentate coordination mode is described and compared with published ones.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Coordination Chemistry
ISSN
0095-8972
e-ISSN
1029-0389
Volume of the periodical
75
Issue of the periodical within the volume
15-16
Country of publishing house
GB - UNITED KINGDOM
Number of pages
14
Pages from-to
2077-2090
UT code for WoS article
000863373400001
EID of the result in the Scopus database
2-s2.0-85141084852