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XRD analysis of nanocrystalline anatase powders prepared by various chemical routes: correlations between micro-structure and crystal structure parameters

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F13%3A10173493" target="_blank" >RIV/00216208:11320/13:10173493 - isvavai.cz</a>

  • Alternative codes found

    RIV/67985858:_____/13:00398859

  • Result on the web

    <a href="http://dx.doi.org/10.1017/S0885715613001061" target="_blank" >http://dx.doi.org/10.1017/S0885715613001061</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1017/S0885715613001061" target="_blank" >10.1017/S0885715613001061</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    XRD analysis of nanocrystalline anatase powders prepared by various chemical routes: correlations between micro-structure and crystal structure parameters

  • Original language description

    Nanocrystalline anatase powders synthesised by various chemical processes as super/subcritical fluid extraction, sol-gel technique and hydrolysis of titanium alkoxides in hydrogen peroxide were studied by X-ray diffraction (XRD) whole profile modelling method (WPPM) in order to reveal correlations between structural and micro-structural parameters as well as sample treatment conditions. Anisotropy of the diffraction line broadening due to truncated bipyramidal shape of anatase crystals was discussed. The hkl-anisotropy can be very strong but also almost negligible in dependence on relative ratio of the crystallite dimensions. The latter was the case for the studied samples. The size of synthesised anatase nanoparticles was within the range 325 nm. Thetheoretical total surface area of crystallites calculated from XRD was in a good correlation with the surface area measured by the nitrogen physisorption up to the temperature 400-450 degrees C, when the particles started to agglomerate.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP108%2F11%2F1539" target="_blank" >GAP108/11/1539: Nanocrystalline materials - X-ray characterization of structure and its thermal stability</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Powder Diffraction

  • ISSN

    0885-7156

  • e-ISSN

  • Volume of the periodical

    28

  • Issue of the periodical within the volume

    S2

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    23

  • Pages from-to

    "S161"-"S183"

  • UT code for WoS article

    000327314000016

  • EID of the result in the Scopus database