All

What are you looking for?

All
Projects
Results
Organizations

Quick search

  • Projects supported by TA ČR
  • Excellent projects
  • Projects with the highest public support
  • Current projects

Smart search

  • That is how I find a specific +word
  • That is how I leave the -word out of the results
  • “That is how I can find the whole phrase”

Structural variability of copper-1,10-phenanthroline?oxovanadate hybrid inorganic?organic compounds

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F06%3A00017824" target="_blank" >RIV/00216224:14310/06:00017824 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11310/06:10506

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Structural variability of copper-1,10-phenanthroline?oxovanadate hybrid inorganic?organic compounds

  • Original language description

    Reactions in the CuSO4?phen?KVO3?H2O?(KOH) systems under non-hydrothermal conditions yielded seven new compounds: [Cu2(H2O)2(OH)2(phen)2][Cu2(OH)2(phen)2(V4O12)].6H2O (3), [Cu2(phen)4(V4O12)].4H2O (4), [Cu2(phen)4(V4O12)].6H2O (5), [Cu2(phen)4(VO3)4].10H2O (6), [Cu(phen)3]2V4O12.phen.22H2O (7), [Cu(phen)(VO3)2] (9) and [Cu2(phen)4(V4O12)].4H2O (12). The prepared compounds were characterized by elemental analyses and IR spectra. The characteristic bands in the IR spectra corresponding to the V?O stretching modes enabled the different oxovanadate groups present in the structures to be unequivocally distinguished. Compounds 3, 4, 5, 6, 7 and 12 were characterized by X-ray single crystal diffraction. The structure of compound 3 consists of isolated dinuclear [(phen)(H2O)Cu(mu-OH)2Cu(phen)(H2O)]2+ ions and [(phen)Cu(OH)2Cu(phen)]2+ moieties attached to Click to view the MathML source rings. The structures of compounds 4, 5 and 12 contain [Cu2(phen)4(V4O12)] clusters with different bonding m

  • Czech name

    Strukturní variabilita hybridních organicko-anorganických měďnato-oxovanadičnatých komplexů

  • Czech description

    Metodami monokrystalové RTG difrakce na 7 nových sloučeninách, [Cu2(H2O)2(OH)2(phen)2] [Cu2(OH)2(phen)2(V4O12)].6H2O, [Cu2(phen)4(V4O12)].4H2O, [Cu2(phen)4(V4O12)].6H2O, [Cu2(phen)4(VO3)4].10H2O, [Cu(phen)3]2V4O12.phen.22H2O, [Cu(phen)(VO3)2] a [Cu2(phen)4(V4O12)].4H2O, byla popsána strukturní variabilita vzájemných vazebných interakcí mezi kationovou a anionovou částí studovaných komplexů.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA203%2F99%2FM037" target="_blank" >GA203/99/M037: Centre of molecular and crystal structures</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2006

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Polyhedron

  • ISSN

    0277-5387

  • e-ISSN

  • Volume of the periodical

    25

  • Issue of the periodical within the volume

    13

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    12

  • Pages from-to

    2491-2502

  • UT code for WoS article

  • EID of the result in the Scopus database