Structural variability of copper-1,10-phenanthroline?oxovanadate hybrid inorganic?organic compounds
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F06%3A00017824" target="_blank" >RIV/00216224:14310/06:00017824 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/06:10506
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Structural variability of copper-1,10-phenanthroline?oxovanadate hybrid inorganic?organic compounds
Original language description
Reactions in the CuSO4?phen?KVO3?H2O?(KOH) systems under non-hydrothermal conditions yielded seven new compounds: [Cu2(H2O)2(OH)2(phen)2][Cu2(OH)2(phen)2(V4O12)].6H2O (3), [Cu2(phen)4(V4O12)].4H2O (4), [Cu2(phen)4(V4O12)].6H2O (5), [Cu2(phen)4(VO3)4].10H2O (6), [Cu(phen)3]2V4O12.phen.22H2O (7), [Cu(phen)(VO3)2] (9) and [Cu2(phen)4(V4O12)].4H2O (12). The prepared compounds were characterized by elemental analyses and IR spectra. The characteristic bands in the IR spectra corresponding to the V?O stretching modes enabled the different oxovanadate groups present in the structures to be unequivocally distinguished. Compounds 3, 4, 5, 6, 7 and 12 were characterized by X-ray single crystal diffraction. The structure of compound 3 consists of isolated dinuclear [(phen)(H2O)Cu(mu-OH)2Cu(phen)(H2O)]2+ ions and [(phen)Cu(OH)2Cu(phen)]2+ moieties attached to Click to view the MathML source rings. The structures of compounds 4, 5 and 12 contain [Cu2(phen)4(V4O12)] clusters with different bonding m
Czech name
Strukturní variabilita hybridních organicko-anorganických měďnato-oxovanadičnatých komplexů
Czech description
Metodami monokrystalové RTG difrakce na 7 nových sloučeninách, [Cu2(H2O)2(OH)2(phen)2] [Cu2(OH)2(phen)2(V4O12)].6H2O, [Cu2(phen)4(V4O12)].4H2O, [Cu2(phen)4(V4O12)].6H2O, [Cu2(phen)4(VO3)4].10H2O, [Cu(phen)3]2V4O12.phen.22H2O, [Cu(phen)(VO3)2] a [Cu2(phen)4(V4O12)].4H2O, byla popsána strukturní variabilita vzájemných vazebných interakcí mezi kationovou a anionovou částí studovaných komplexů.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F99%2FM037" target="_blank" >GA203/99/M037: Centre of molecular and crystal structures</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2006
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Polyhedron
ISSN
0277-5387
e-ISSN
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Volume of the periodical
25
Issue of the periodical within the volume
13
Country of publishing house
GB - UNITED KINGDOM
Number of pages
12
Pages from-to
2491-2502
UT code for WoS article
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EID of the result in the Scopus database
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