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(N,N,N',N'',N''-Pentamethyldiethylenetriamine-[kappa]3N,N',N'')(trithiocyanurato-[kappa]2N,S)zinc(II)

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F07%3A00021953" target="_blank" >RIV/00216224:14310/07:00021953 - isvavai.cz</a>

  • Alternative codes found

    RIV/61989592:15310/07:00004655

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    (N,N,N',N'',N''-Pentamethyldiethylenetriamine-[kappa]3N,N',N'')(trithiocyanurato-[kappa]2N,S)zinc(II)

  • Original language description

    The structure of the title compound, [Zn(C9H23N3)(C3HN3S3)], consists of discrete molecules connected by N-H...S hydrogen bonds into centrosymmetric dimers. The ZnII atom is pentacoordinated in a deformed trigonal-bipyramidal geometry by three N atoms ofa tridentate N,N,N',N'',N''-pentamethyldiethylenetriamine ligand, and one S and one N atoms of a trithiocyanurate dianion bonded as a bidentate ligand. The crystal structure is further stabilized by close contacts of the types C-H...S and C-H...N.

  • Czech name

    Krystalová struktura pentamethyldiethylentriamino-trithiocyanurato- zinečnatého komplexu

  • Czech description

    Struktura titulního komplexu, [Zn(C9H23N3)(C3HN3S3)], se skládá z molekul spojených N-H...S vodíkovými můstky do formy centrosymetrických dimerů. Atom Zn(II) je 5x koordinovaný. Jeho koordinační okolí je možné popsat jako deformovanou trojbokou bipyramidu definovanou 3 N atomy pentamethyldiethylenetriaminu a jedním atomem S a jedním atomem N z trithiocyanurového dianionu působícího jako bidentátní ligand. Struktura je dále stabilizovaná nevazebnými kontakty typu C-H...S a C-H...N.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2007

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Acta Crystallographica Section E: Structure Reports Online

  • ISSN

    1600-5368

  • e-ISSN

  • Volume of the periodical

    63

  • Issue of the periodical within the volume

    3

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    3

  • Pages from-to

    "m725"-"m727"

  • UT code for WoS article

  • EID of the result in the Scopus database