The synthesis and characterization of new aminoadamantane derivatives of hexachloro-cyclo-triphosphazene
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F08%3A00024203" target="_blank" >RIV/00216224:14310/08:00024203 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
The synthesis and characterization of new aminoadamantane derivatives of hexachloro-cyclo-triphosphazene
Original language description
The reactions of hexachloro-cyclo-triphosphazene P3N3Cl6 (1) with 1-aminoadamantane (amantadine, Ad-NH2) and 1-amino-3,5-dimethyladamantane (memantine, Mem) were studied. New geminally substituted phosphazene derivatives, P3N3Cl4(NH-Ad)2 (2), P3N3Cl2(NH-Ad)4 (3) and P3N3Cl2(Mem)4 (4), were prepared. The substances 3 and 4 were fully characterized by 31P NMR and IR spectroscopies and elemental analysis. Molecular and crystal structures of 2,3,4 were determined by X-ray diffraction. The compounds are triclinic, space group . Compound 3 crystallized from dichloromethane as a solvate.
Czech name
Syntéza a charakterizace nových aminoadamantanových derivátů hexachlorocyklotrifosfazenu
Czech description
Byla studována reakce hexachlorocyklotrifosfazenu s 1-aminoadamantanem a 1-amino-3,5-dimethyladamantanem. Byly připraveny nové geminálně substituované deriváty P3N3Cl4(NH-Ad)2 (2), P3N3Cl2(NH-Ad)4 (3) and P3N3Cl2(Mem)4 (4). Sloučeniny 3 a 4 byly charakterizovány spektroskopicky, u sloučenin 2-4 byla stanovena molekulová a krystalová struktura.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/KAN101630651" target="_blank" >KAN101630651: Preparation of nano-films and nano-coatings on textiles using plasma surface treatment at atmospheric pressure</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2008
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Polyhedron
ISSN
0277-5387
e-ISSN
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Volume of the periodical
2008
Issue of the periodical within the volume
27
Country of publishing house
CZ - CZECH REPUBLIC
Number of pages
6
Pages from-to
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UT code for WoS article
000257533800008
EID of the result in the Scopus database
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