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Synthesis of a new polymorph in [Cu(pyridine-2-carboxylate)(2)] system

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F08%3A00027233" target="_blank" >RIV/00216224:14310/08:00027233 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis of a new polymorph in [Cu(pyridine-2-carboxylate)(2)] system

  • Original language description

    Single crystal X-ray studies on a doubly carboxylate bridged {[Cu(pic)(2)].2H(2)O}(n) (1) (pic = pyridine-2-carboxylate) polymeric chains extending along the crystallographic a axis reveal that adjacent polymeric chains are joined by the lattice water chains running parallel to the polymeric chain leading to a 2D sheet in the (101) plane. The successive sheets are interdigitated and glued to each other by a novel C=O...pi interaction into a 3D supramolecular motif. The complex (1) can be regarded as a pseudo-polymorph of [Cu(pic)(2)](n) which has been realized in two forms, violet (2) and blue-violet (3) from methanol.

  • Czech name

    Syntéza nové polyfmorfní formy měďnatého systému [Cu(pyridine-2-carboxylate)(2)]

  • Czech description

    V článku je popisována nová, třetí krystalická pseudo-polyforma titulního měďnatého komplexu

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2008

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY

  • ISSN

    0376-4710

  • e-ISSN

  • Volume of the periodical

    47

  • Issue of the periodical within the volume

    11

  • Country of publishing house

    IN - INDIA

  • Number of pages

    5

  • Pages from-to

  • UT code for WoS article

    000261111200006

  • EID of the result in the Scopus database