Facile dehalogenation of halogenated anilines and their derivatives using Al-Ni alloy in alkaline aqueous solution

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F11%3A00052877" target="_blank" >RIV/00216224:14310/11:00052877 - isvavai.cz</a>

Alternative codes found

RIV/00216275:25310/11:39892295

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Facile dehalogenation of halogenated anilines and their derivatives using Al-Ni alloy in alkaline aqueous solution

Original language description

The article describes the simple hydrodehalogenation of halogenated anilines and their derivatives by the action of Raney aluminium-nickel alloy in aqueous alkaline solution at room temperature. The reaction course was monitored by means of 1H nuclear magnetic resonance spectroscopy and GCMS. The reduction method described was satisfactorily proved for dehalogenation of polyhalogenated anilines in the multiphase dimethoxymethane/aqueous NaOH/Al-Ni reaction mixture. Dehalogenation under multi-phase conditions was demonstrated for the preparation of ortho-alkylated anilines from simply available 2-substituted-4- chloroanilines.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

<a href="/en/project/GP203%2F07%2FP248" target="_blank" >GP203/07/P248: Bimetallic alloys combined with humic acids for contaminated water treatment</a><br>

Continuities

S - Specificky vyzkum na vysokych skolach

Publication year

2011

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Central European Journal of Chemistry

ISSN

1895-1066

e-ISSN

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Volume of the periodical

9

Issue of the periodical within the volume

4

Country of publishing house

DE - GERMANY

Number of pages

8

Pages from-to

590-597

UT code for WoS article

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EID of the result in the Scopus database

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