The first X-ray crystal structure of a mercury(II) complex with an SP(N)(3)-based ligand: Synthesis and crystal structure of SP(NC5H10)(3) and [Hg{SP(NC5H10)(3)}Cl-2](2)

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F19%3A00113454" target="_blank" >RIV/00216224:14310/19:00113454 - isvavai.cz</a>
Result on the web
<a href="https://www.tandfonline.com/doi/abs/10.1080/10426507.2018.1487427" target="_blank" >https://www.tandfonline.com/doi/abs/10.1080/10426507.2018.1487427</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/10426507.2018.1487427" target="_blank" >10.1080/10426507.2018.1487427</a>

Result language
angličtina
Original language name
The first X-ray crystal structure of a mercury(II) complex with an SP(N)(3)-based ligand: Synthesis and crystal structure of SP(NC5H10)(3) and [Hg{SP(NC5H10)(3)}Cl-2](2)
Original language description
The synthesis, spectral characteristics (IR and NMR), elemental analysis and X-ray crystal structure of phosphorothioic triamide SP(NC5H10)(3) (1) and its dinuclear mercury(II) complex [Hg-2(-Cl)(2)(Cl)(2){SP(NC5H10)(3)}(2)] (2) were investigated. A survey using the Cambridge Structural Database (CSD, version 5.38, May 2017) shows structures of coordination compounds of Au, Ag, Cd, Cu, Li, Mo, Ni, Pd, Te, Ti, Zn, and Zr with sulfur-donor SP(N)(3)-based ligands; the complex 2 is the first example of a mercury complex with the SP(N)(3)-based ligand studied by X-ray crystallography. Valence bond calculation was performed for the Hg-S bond in 2 and compared with the Hg-O bond in the only structure with a Cl2Hg-OP(N)(3) structural motive in the CSD. The calculation confirms a more covalent nature of the Hg-S bond with respect to the Hg-O bond made by the EP(N)(3)-based ligands (E=S, O). The supramolecular structures based on C-HS=P contacts in 1 and C-HS?P and C-HCl-Hg assemblies in 2 are discussed.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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