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Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14740%2F12%3A00079730" target="_blank" >RIV/00216224:14740/12:00079730 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s11243-011-9569-9" target="_blank" >http://dx.doi.org/10.1007/s11243-011-9569-9</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s11243-011-9569-9" target="_blank" >10.1007/s11243-011-9569-9</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study

  • Original language description

    A series of distorted square planar palladium(II) complexes with dithiocarbamic acids of general formula [Pd(L)(2)], where L = 4-methylpiperazine-l-carbodithioic acid anion, morpholine-4-carbodithioic acid anion or 4-benzylpiperidine-l-carbodithioic acidanion for complexes 1a, 1b and 1c, respectively, have been synthesized. The complexes were characterized by physicochemical and spectroscopic methods; in addition, the structure of complex 1a was characterized by single crystal X-ray crystallography. The interaction of these palladium complexes with CT-DNA was investigated with the help of absorption and emission spectroscopy. The association constant K-b was deduced from the absorption spectra, while the number of binding sites and the binding constant were calculated from the fluorescence quenching data. The results suggest an intercalative interaction of the complexes with CT-DNA.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Transition Metal Chemistry

  • ISSN

    0340-4285

  • e-ISSN

  • Volume of the periodical

    37

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    7

  • Pages from-to

    155-161

  • UT code for WoS article

    000302376000005

  • EID of the result in the Scopus database