Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14740%2F12%3A00079730" target="_blank" >RIV/00216224:14740/12:00079730 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s11243-011-9569-9" target="_blank" >http://dx.doi.org/10.1007/s11243-011-9569-9</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s11243-011-9569-9" target="_blank" >10.1007/s11243-011-9569-9</a>
Alternative languages
Result language
angličtina
Original language name
Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study
Original language description
A series of distorted square planar palladium(II) complexes with dithiocarbamic acids of general formula [Pd(L)(2)], where L = 4-methylpiperazine-l-carbodithioic acid anion, morpholine-4-carbodithioic acid anion or 4-benzylpiperidine-l-carbodithioic acidanion for complexes 1a, 1b and 1c, respectively, have been synthesized. The complexes were characterized by physicochemical and spectroscopic methods; in addition, the structure of complex 1a was characterized by single crystal X-ray crystallography. The interaction of these palladium complexes with CT-DNA was investigated with the help of absorption and emission spectroscopy. The association constant K-b was deduced from the absorption spectra, while the number of binding sites and the binding constant were calculated from the fluorescence quenching data. The results suggest an intercalative interaction of the complexes with CT-DNA.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Transition Metal Chemistry
ISSN
0340-4285
e-ISSN
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Volume of the periodical
37
Issue of the periodical within the volume
2
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
7
Pages from-to
155-161
UT code for WoS article
000302376000005
EID of the result in the Scopus database
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