Inclusion compounds of cystostatic active (C5H5)2 VCl2 and (CH3C5H4)2 VCl2 with a-, b- and c- cyclodextrines: Synthesis, EPR study and microbiological behavior toward Escherichia coli.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F05%3A00001636" target="_blank" >RIV/00216275:25310/05:00001636 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Inclusion compounds of cystostatic active (C5H5)2 VCl2 and (CH3C5H4)2 VCl2 with a-, b- and c- cyclodextrines: Synthesis, EPR study and microbiological behavior toward Escherichia coli.

Original language description

The inclusion of vanadocene dichloride (VDC) and 1,1'-dimethyl vanadocene dichloride (MeVDC) into cyclodextrines (a-CD, b-CD and c-CD) was studied by EPR spectroscopy. It was found that VDC and MeVDC with b-CD and c-CD form true inclusion compounds, butwith a-CD, VDC and MeVDC gave only fine dispersion mixtures. The inclusion was validated by anisotropic EPR spectra of solid samples. In addition, the antimicrobial behavior (against E. coli) of each of the complexes was determined. It was established that not only did VDC and MeVDC cause elongation of E. coli, but also the new vanadocene inclusion complexes were effective in this regard.

Czech name

Inclusion compounds of cystostatic active (C5H5)2 VCl2 and (CH3C5H4)2 VCl2 with a-, b- and c- cyclodextrines: Synthesis, EPR study and microbiological behavior toward Escherichia coli.

Czech description

The inclusion of vanadocene dichloride (VDC) and 1,1'-dimethyl vanadocene dichloride (MeVDC) into cyclodextrines (a-CD, b-CD and cCD) was studied by EPR spectroscopy. It was found that VDC and MeVDC with b-CD and c-CD form true inclusion compounds, but with a-CD, VDC and MeVDC gave only fine dispersion mixtures. The inclusion was validated by anisotropic EPR spectra of solid samples. In addition, the antimicrobial behavior (against E. coli) of each of the complexes was determined. It was established that not only did VDC and MeVDC cause elongation of E. coli, but also the new vanadocene inclusion complexes were effective in this regard.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2005

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Central European Journal of Chemistry

ISSN

1644-3624

e-ISSN

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Volume of the periodical

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Issue of the periodical within the volume

1

Country of publishing house

PL - POLAND

Number of pages

10

Pages from-to

72-81

UT code for WoS article

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EID of the result in the Scopus database

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