The stannylene {2,6-(Me2NCH2)(2)C6H3} SnCl as a Ligand in Transition Metal Complexes of Palladium, Ruthenium, Rhodium
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F09%3A00008340" target="_blank" >RIV/00216275:25310/09:00008340 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
The stannylene {2,6-(Me2NCH2)(2)C6H3} SnCl as a Ligand in Transition Metal Complexes of Palladium, Ruthenium, Rhodium
Original language description
The cleavage of the chloride bridge in the dimeric transition complexes [(?3-C3H5)Pd]2(?-Cl)2, [(?6-benzene)RuCl]2(?-Cl)2, [(?6-cymene)RuCl]2(?-Cl)2, [(C?)3RuCl]2(?-Cl)2, and [(C?)2Rh]2(?-Cl)2 by heteroleptic LSnCl stannylene (L is a N,C,N-pincer ligand[2,6-(Me2NCH2)2C6H3]) resulted in the isolation of PdII-SnII, RuII-SnII, and RhI-SnII complexes [Pd(?3-C3H5)(LSnCl)Cl] (2), [Ru(?6-benzene)(LSnCl)Cl2] (3), [Ru(?6-cymene)(LSnCl)Cl2] (4), [Ru(CO)3(LSnCl)Cl2] (5), and [Rh-(CO)2(LSnCl)Cl] (6). All compoundswere characterized by NMR and IR spectroscopy, and the structures of compounds 2 and 4 were determined by X-ray diffraction analysis. The structure of a rare monomeric RhII-SnII complex, [Rh(LSnCl)2Cl2] (7), the final decomposition product of RhI-SnII complex 6, is also reported.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2009
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
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Volume of the periodical
28
Issue of the periodical within the volume
16
Country of publishing house
US - UNITED STATES
Number of pages
6
Pages from-to
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UT code for WoS article
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EID of the result in the Scopus database
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