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The stannylene {2,6-(Me2NCH2)(2)C6H3} SnCl as a Ligand in Transition Metal Complexes of Palladium, Ruthenium, Rhodium

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F09%3A00008340" target="_blank" >RIV/00216275:25310/09:00008340 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    The stannylene {2,6-(Me2NCH2)(2)C6H3} SnCl as a Ligand in Transition Metal Complexes of Palladium, Ruthenium, Rhodium

  • Original language description

    The cleavage of the chloride bridge in the dimeric transition complexes [(?3-C3H5)Pd]2(?-Cl)2, [(?6-benzene)RuCl]2(?-Cl)2, [(?6-cymene)RuCl]2(?-Cl)2, [(C?)3RuCl]2(?-Cl)2, and [(C?)2Rh]2(?-Cl)2 by heteroleptic LSnCl stannylene (L is a N,C,N-pincer ligand[2,6-(Me2NCH2)2C6H3]) resulted in the isolation of PdII-SnII, RuII-SnII, and RhI-SnII complexes [Pd(?3-C3H5)(LSnCl)Cl] (2), [Ru(?6-benzene)(LSnCl)Cl2] (3), [Ru(?6-cymene)(LSnCl)Cl2] (4), [Ru(CO)3(LSnCl)Cl2] (5), and [Rh-(CO)2(LSnCl)Cl] (6). All compoundswere characterized by NMR and IR spectroscopy, and the structures of compounds 2 and 4 were determined by X-ray diffraction analysis. The structure of a rare monomeric RhII-SnII complex, [Rh(LSnCl)2Cl2] (7), the final decomposition product of RhI-SnII complex 6, is also reported.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2009

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Organometallics

  • ISSN

    0276-7333

  • e-ISSN

  • Volume of the periodical

    28

  • Issue of the periodical within the volume

    16

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    6

  • Pages from-to

  • UT code for WoS article

  • EID of the result in the Scopus database