Chromiumpentacarbonyl-Coordinated Organotin(II) Cation.

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F11%3A39892006" target="_blank" >RIV/00216275:25310/11:39892006 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/om200122m" target="_blank" >http://dx.doi.org/10.1021/om200122m</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om200122m" target="_blank" >10.1021/om200122m</a>

Result language
angličtina
Original language name
Chromiumpentacarbonyl-Coordinated Organotin(II) Cation.
Original language description
The synthesis of the novel chromiumpentacarbonyl complex [2,6-(MeOCH2)2- C6H3](Cl) SnCr(CO)5 (1) is reported. Compound 1 was used for the synthesis of novel chromiumpentacarbonyl coordinated organotin(II) cations [{2,6-(MeOCH2)2C6H3}SnCr-CO)5] (X = OTf or CB11H12). The strongly Lewis acidic tin(II) center of the latter organotin(II) cations coordinates H2O or THF molecules yielding the corresponding organotin(II) cations [{2,6-(MeOCH2)2C6H3}(H2O)SnCr(CO)5]? [OTf](2) and [{2,6-(MeOCH2)2C6H3}(H2O)SnCr(CO)5]? [CB11H12] (3). Compounds 13 were characterized by means of elemental analyses, 1H, 13C, 119Sn NMR spectroscopies, and single crystal X-ray diffraction analysis.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GAP207%2F10%2F0215" target="_blank" >GAP207/10/0215: Structure, Properties and the Use of C,N-, Y,C,Y-chelated Organometallic and Related Metal Complexes</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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