Deamination of N -} Sn-Coordinated Organotin(II) Hydroxide: Formation of a New C-O Covalent Bond

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898824" target="_blank" >RIV/00216275:25310/14:39898824 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/ejic.201402836" target="_blank" >http://dx.doi.org/10.1002/ejic.201402836</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.201402836" target="_blank" >10.1002/ejic.201402836</a>

Result language
angličtina
Original language name
Deamination of N -} Sn-Coordinated Organotin(II) Hydroxide: Formation of a New C-O Covalent Bond
Original language description
The synthesis of the pentacarbonylchromium complex [{2,6-(Me2NCH2)(2)C6H3}(Cl) SnCr(CO)(5)] is reported. Starting with this compound, organotin(II) pentacarbonylchromium methoxide [{2,6-(Me2NCH2)(2)C6H3}(OMe)SnCr(CO)(5)] was prepared and used for the synthesis of dimeric N -} Sn intramolecularly coordinated organotin(II) pentacarbonylchromium hydroxide [{2,6-(Me2NCH2)(2)C6H3}Sn(mu-OH)Cr(CO)(5)](2) by easy hydrolytic protocol. In addition, acid-base-type reaction of this latter compound with HOTf provided unprecedented cyclization product [6-(Me2NCH2)-2,3-(C6H3CH2OSn)Cr-(CO)(5)](2). The cyclization process is accompanied by the formation of a new C-O covalent bond along with the elimination of Me2NH.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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