Synthesis and Structure of NCN-Chelated Organobismuth(III) Bis-Pentasulfide

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F12%3A39895565" target="_blank" >RIV/00216275:25310/12:39895565 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/zaac.201100515" target="_blank" >http://dx.doi.org/10.1002/zaac.201100515</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/zaac.201100515" target="_blank" >10.1002/zaac.201100515</a>

Result language
angličtina
Original language name
Synthesis and Structure of NCN-Chelated Organobismuth(III) Bis-Pentasulfide
Original language description
Organobismuth(III) sulfide (1) containing the NCN pincer type chelating ligand L {L = [2, 6-(CH2NMe2)2C6H3]} reacts with one molar equivalent of elemental sulfur to give the unprecedented cyclic bis-pentasulfide LBi(mu-S5)2BiL (2) with the central twelve-membered ring Bi2S10. Compound 2 was obtained as stable orange crystals and was characterized by the help of elemental analysis, X-ray diffraction technique, IR, and Raman spectroscopy.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GAP207%2F10%2F0130" target="_blank" >GAP207/10/0130: N,C,N Chelated Chalcogenides of Heavier Group 14 and 15 Elements</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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