Acyl-Functionalized Molybdenum Compounds [(éta3-C3H5)(éta5-Cp)Mo(CO)2]: An Experimental Study Including the X-ray Structure of a Rare endo Conformer

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898091" target="_blank" >RIV/00216275:25310/14:39898091 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1002/ejic.201402700" target="_blank" >http://dx.doi.org/10.1002/ejic.201402700</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/ejic.201402700" target="_blank" >10.1002/ejic.201402700</a>

Result language

angličtina

Original language name

Acyl-Functionalized Molybdenum Compounds [(éta3-C3H5)(éta5-Cp)Mo(CO)2]: An Experimental Study Including the X-ray Structure of a Rare endo Conformer

Original language description

A series of new acyl-functionalized molybdenum(II) complexes [(éta3-C3H5)(éta5-C5H4COR)Mo(CO)2] have been successfully synthesized and crystallographically characterized, and the relationship between the reactivity and electronic properties of these organometallic compounds has been studied in detail. The X-ray analysis revealed [(éta3-C3H5)(éta5-C5H4COCF3)Mo(CO)2] to exist as a rare endo conformer, the first time that this structure has been observed in the crystal lattice of a [(éta3-C3H5)(éta5-Cp?)Mo(CO)2] (Cp? = substituted Cp) complex without any disorder. It has also been demonstrated that the derivatives bearing very strong electron-withdrawing acyl groups (e.g., -CHO, -COCF3) show different outcomes in the protonation reactions compared with the parent cyclopentadienyl compound or derivatives bearing less electron-withdrawing groups (e.g., -COMe, -COPh). This study has also revealed the increased reactivity of the formyl derivative [(éta3-C3H5)(éta5-C5H4CHO)Mo(CO)2] towards aro

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2014

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

European Journal of Inorganic Chemistry

ISSN

1434-1948

e-ISSN

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Volume of the periodical

Neuveden

Issue of the periodical within the volume

34

Country of publishing house

DE - GERMANY

Number of pages

13

Pages from-to

5895-5907

UT code for WoS article

000345771700012

EID of the result in the Scopus database

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