Syntheses, crystal structures, and IR spectra of isonicotinamide-isonicotinamidium bis(isonicotinamide)-tetrakis(isothiocyanato)ferrate(III) and isonicotinamidium chloride

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898450" target="_blank" >RIV/00216275:25310/14:39898450 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1080/00958972.2014.917634" target="_blank" >http://dx.doi.org/10.1080/00958972.2014.917634</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1080/00958972.2014.917634" target="_blank" >10.1080/00958972.2014.917634</a>

Result language

angličtina

Original language name

Syntheses, crystal structures, and IR spectra of isonicotinamide-isonicotinamidium bis(isonicotinamide)-tetrakis(isothiocyanato)ferrate(III) and isonicotinamidium chloride

Original language description

Reaction of iron(III) thiocyanate with isonicotinamide (inia) in ethanol leads to formation of a dark red, air stabile crystalline iron(III) compound of composition [iniaH center dot inia][Fe(inia)(2)(NCS-N)(4)]. Single-crystal X-ray diffraction analysisshows the triclinic P-1 space group with unit cell parameters: a = 8.2440(4) angstrom, b = 9.5540(3) angstrom, c = 11.2590(5) angstrom, alpha = 93.945(4)degrees, beta = 95.554(4)degrees, gamma = 96.285(3)degrees, and Z = 1. The iron compound contains [iniaH center dot inia](+) cations and [Fe(inia)(2)(NCS-N)(4)]-anions, which are held together by ionic interactions and hydrogen bonding. The Fe(III) is octahedrally coordinated by six nitrogens, four from NCS- in the equatorial plane and two from inia occupying axial positions. The [iniaH]Cl has been formed by reaction of inia with hydrochloric acid. [iniaH]Cl crystallized in the monoclinic C2/c space group with unit cell parameters: a = 25.156(5) angstrom, b = 5.095 (1) angstrom, c = 12

Czech name

—

Czech description

—

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

—

Project

—

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2014

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Coordination Chemistry

ISSN

0095-8972

e-ISSN

—

Volume of the periodical

67

Issue of the periodical within the volume

9

Country of publishing house

GB - UNITED KINGDOM

Number of pages

12

Pages from-to

1652-1663

UT code for WoS article

000340149000013

EID of the result in the Scopus database

—