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Optical, electrical and morphological study of PEDOT:PSS single layers spiral-bar coated with various secondary doping solvents

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39902662" target="_blank" >RIV/00216275:25310/17:39902662 - isvavai.cz</a>

  • Alternative codes found

    RIV/28778758:_____/17:N0000015

  • Result on the web

    <a href="http://www.sciencedirect.com/science/article/pii/S0379677917300978" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0379677917300978</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.synthmet.2017.04.006" target="_blank" >10.1016/j.synthmet.2017.04.006</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Optical, electrical and morphological study of PEDOT:PSS single layers spiral-bar coated with various secondary doping solvents

  • Original language description

    The electrical, morphological and optical properties of a series of spiral-bar coated single layers of PEDOT:PSS influenced by the addition of 10 different secondary dopants have been studied. The optical properties of these samples have been analyzed over a broad spectral range from 190 nm to 30 microm using spectroscopic ellipsometry and transmittance. The isotropic model fits the ellipsometric data quite well. No substantial differences in the optical constants were obtained, despite a difference being expected from the significant change of specific electrical conductivity (by 3 orders of magnitude). In the infrared part of spectra, the multiple Lorentz oscillators’ model was used instead of the frequently used Drude model by applying narrow oscillators for molecular vibrations together with the broad oscillators describing electronic transitions in the mid-gap states. The geometrical parameters obtained from ellipsometry evaluation have been found to be in good agreement with standard mechanical characterization probes (profilometry and AFM). The highest value of the specific electric conductivity, 78.3 S/cm, was achieved by using n-methyl methanamide as a secondary dopant. The research results confirm that spectroscopic ellipsometry is a valuable tool for characterization of the functional layers used in printed electronics.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10404 - Polymer science

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Synthetic Metals

  • ISSN

    0379-6779

  • e-ISSN

  • Volume of the periodical

    227

  • Issue of the periodical within the volume

    May

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    9

  • Pages from-to

    139-147

  • UT code for WoS article

    000401376700018

  • EID of the result in the Scopus database

    2-s2.0-85017273454