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A zwitterionic (poly)methacrylate monolithic capillary column with dual HILIC – reversed-phase mechanism for uni- and two-dimensional HPLC

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39911247" target="_blank" >RIV/00216275:25310/17:39911247 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    A zwitterionic (poly)methacrylate monolithic capillary column with dual HILIC – reversed-phase mechanism for uni- and two-dimensional HPLC

  • Original language description

    Sulfobetaine zwitterionic monolithic columns were synthesized by in-situ polymerization (in fused silica capillaries) of a N,N-dimethyl-N-metacrylaloxyethyl-N-(3-sulfopropyl) ammonium betaine (MEDSA) functional monomer in combination with different cross-linking monomers. From among the ten cross-linkers tested, Bisphenol A glycerolate dimethacrylate provides monolithic capillary column with the best chromatographic efficiency (60 000 – 70 000 theoretical plates per meter). The respective columns show excellent column-to-column reproducibility of pore morphology, separation selectivity, good permeability and low mass transfer resistance, so that being suitable for fast and selective separation of various samples.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>ost</sub> - Miscellaneous article in a specialist periodical

  • CEP classification

  • OECD FORD branch

    10404 - Polymer science

Result continuities

  • Project

    <a href="/en/project/GAP206%2F12%2F0398" target="_blank" >GAP206/12/0398: Two-dimensional separations in liquid media</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Scientific Papers of the University of Pardubice, Series A, Faculty of Chemical Technology

  • ISSN

    1211-5541

  • e-ISSN

  • Volume of the periodical

    23

  • Issue of the periodical within the volume

    květen

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    20

  • Pages from-to

    51-70

  • UT code for WoS article

  • EID of the result in the Scopus database