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Investigation of Thiaborane closo-nido Conversion Pathways Promoted by N-Heterocyclic Carbenes

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F19%3A39915529" target="_blank" >RIV/00216275:25310/19:39915529 - isvavai.cz</a>

  • Alternative codes found

    RIV/61388980:_____/19:00502090 RIV/61388963:_____/19:00502090

  • Result on the web

    <a href="https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b03037" target="_blank" >https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b03037</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/acs.inorgchem.8b03037" target="_blank" >10.1021/acs.inorgchem.8b03037</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Investigation of Thiaborane closo-nido Conversion Pathways Promoted by N-Heterocyclic Carbenes

  • Original language description

    The 12-X-closo-SB11H10 (X = H or I) thiaboranes react with one or two molar equivalents of various N-heterocyclic carbenes (NHCs) to give the deprotonated 12-vertex species of [12-X-S11H9 center dot NHC](-)[NHC-H](+)composition as kinetic products. The use of one molar equivalent of a sterically more hindered NHC reactant leads to the formation of 12-X-SB11H10 center dot NHC adducts with a heavily distorted cage and the nido electron count. Further reaction of 12-I-SB11H10 center dot NHC to deboronated 12-X-SB10H9 center dot NHC proceeds in acetone to complete the closo-nido reaction pathway under the thermodynamic control. The structures of all compounds have been investigated by NMR spectroscopy and diffraction techniques. The results are supported by theoretical methods.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

    <a href="/en/project/GA17-08045S" target="_blank" >GA17-08045S: Getting stronger together: exo-substituted heteroboranes and their adducts as suitable motifs for exploration of non-covalent interactions</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Inorganic Chemistry

  • ISSN

    0020-1669

  • e-ISSN

  • Volume of the periodical

    58

  • Issue of the periodical within the volume

    4

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    12

  • Pages from-to

    2471-2482

  • UT code for WoS article

    000459367300029

  • EID of the result in the Scopus database