Investigation of Thiaborane closo-nido Conversion Pathways Promoted by N-Heterocyclic Carbenes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F19%3A39915529" target="_blank" >RIV/00216275:25310/19:39915529 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/19:00502090 RIV/61388963:_____/19:00502090
Result on the web
<a href="https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b03037" target="_blank" >https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b03037</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.inorgchem.8b03037" target="_blank" >10.1021/acs.inorgchem.8b03037</a>
Alternative languages
Result language
angličtina
Original language name
Investigation of Thiaborane closo-nido Conversion Pathways Promoted by N-Heterocyclic Carbenes
Original language description
The 12-X-closo-SB11H10 (X = H or I) thiaboranes react with one or two molar equivalents of various N-heterocyclic carbenes (NHCs) to give the deprotonated 12-vertex species of [12-X-S11H9 center dot NHC](-)[NHC-H](+)composition as kinetic products. The use of one molar equivalent of a sterically more hindered NHC reactant leads to the formation of 12-X-SB11H10 center dot NHC adducts with a heavily distorted cage and the nido electron count. Further reaction of 12-I-SB11H10 center dot NHC to deboronated 12-X-SB10H9 center dot NHC proceeds in acetone to complete the closo-nido reaction pathway under the thermodynamic control. The structures of all compounds have been investigated by NMR spectroscopy and diffraction techniques. The results are supported by theoretical methods.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA17-08045S" target="_blank" >GA17-08045S: Getting stronger together: exo-substituted heteroboranes and their adducts as suitable motifs for exploration of non-covalent interactions</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganic Chemistry
ISSN
0020-1669
e-ISSN
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Volume of the periodical
58
Issue of the periodical within the volume
4
Country of publishing house
US - UNITED STATES
Number of pages
12
Pages from-to
2471-2482
UT code for WoS article
000459367300029
EID of the result in the Scopus database
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