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Several salicylatocopper(II) complexes with diethylnicotinamide: Preparation, structure, spectral properties and Hirshfeld surface analysis

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F19%3A39915535" target="_blank" >RIV/00216275:25310/19:39915535 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S0022286018314996?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0022286018314996?via%3Dihub</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.molstruc.2018.12.066" target="_blank" >10.1016/j.molstruc.2018.12.066</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Several salicylatocopper(II) complexes with diethylnicotinamide: Preparation, structure, spectral properties and Hirshfeld surface analysis

  • Original language description

    The little change of the reaction conditions led to formation four monomeric copper (II) complexes of different hydrate formula [Cu(XSal)(2)(dena)(2)(H2O)(x)] (where x = 0 for XSal = 3,5-dichlorosalicylate; x = 1 for XSal = 5-methylsalicylate or x = 2 for XSal = 4-chlorosalicylate resp. 3,5-dichlorosalicylate; dena = N,N-diethylnicotinamide) and two anhydrous polymeric complexes [Cu(XSal)(2)(dena)(2)](n) (where XSal = 5-bromosalicylate or XSal = 4-methoxysalicylate). The monomeric complexes build up 1D chains and/or 2D supramolecular network. The polymeric ones constitute 1D coordination polymers. The intermolecular interactions were studied by Hirshfeld surface analysis. Four different coordination modes of anion were observed in compounds and they are in good relation to their spectral information. The EPR spectra of all the complexes were measured at room temperature. The g-factor values evaluated from the axially symmetric Cu(II) EPR spectra fulfilled an usual relation of g(//) &gt;g perpendicular to&gt; 2.0023, which is consistent with d(x)(2)-(2)(y) ground electronic state and which indicates the coordination sphere of the distorted tetragonal symmetry for copper (II) ions.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Molecular Structure

  • ISSN

    0022-2860

  • e-ISSN

  • Volume of the periodical

    1181

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    10

  • Pages from-to

    373-382

  • UT code for WoS article

    000458612300042

  • EID of the result in the Scopus database