Access to the most sterically crowded anilines via non-catalysed C-C coupling reactions
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F20%3A39916646" target="_blank" >RIV/00216275:25310/20:39916646 - isvavai.cz</a>
Result on the web
<a href="https://pubs.rsc.org/en/content/articlelanding/2020/cc/c9cc09497k#!divAbstract" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2020/cc/c9cc09497k#!divAbstract</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c9cc09497k" target="_blank" >10.1039/c9cc09497k</a>
Alternative languages
Result language
angličtina
Original language name
Access to the most sterically crowded anilines via non-catalysed C-C coupling reactions
Original language description
Variously substituted 2,6-bis(1,1-diarylethyl)anilines and 2,6-bis(trityl)anilines were prepared by a three-step high-yield process. Dimethyl-2-aminoisophtalate was modified by reaction with arylmagnesium bromides, and the hydroxy-derivatives obtained were etherified. Under the non-catalysed C-C coupling protocol, the formed bis[methyl(methoxy)diaryl]anilines react with various Grignard reagents to give highly substituted products. The buried volumes around the central nitrogen atom of the prepared compounds exceed the parameters for the known most sterically hindered anilines by about 20%.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemical Communications
ISSN
1359-7345
e-ISSN
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Volume of the periodical
56
Issue of the periodical within the volume
16
Country of publishing house
GB - UNITED KINGDOM
Number of pages
4
Pages from-to
2487-2490
UT code for WoS article
000519582800022
EID of the result in the Scopus database
2-s2.0-85080111664