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High pressure modification of the simple automated liquid chromatographic system for splitless nano column gradient separations

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F13%3APU106482" target="_blank" >RIV/00216305:26310/13:PU106482 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    High pressure modification of the simple automated liquid chromatographic system for splitless nano column gradient separations

  • Original language description

    In this work we have modified our concept of simple splitless gradient liquid chromatographic system for micro and nano columns with backpressure up to 50 bar. Presented configuration allows us to run analysis under the pressure up to 400 bar. Experimental configuration consists of an OEM programmable syringe pump equipped with a 250-ul high-pressure syringe and ten-port selector valve. High pressure syringe is connected to central port of selector valve via 0.5 meter long PEEK capillary of 380 um i. d.fixed in horizontal plane. PEEK capillary here serves as gradient generator as well as gradient loop and as sample loop. Mobile phase gradients are created by successive sucking of defined volumes of four water-acetonitrile solutions with gradually changing acetonitrile concentration into the PEEK capillary. Sharp mobile phase boundaries fade out while passing through the valve body and due to the parabolic profile of laminar flow as well as due to diffusion. Available linear gradients

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CB - Analytical chemistry, separation

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Chemické listy

  • ISSN

    1213-7103

  • e-ISSN

  • Volume of the periodical

    107

  • Issue of the periodical within the volume

    s3

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    3

  • Pages from-to

    438-440

  • UT code for WoS article

  • EID of the result in the Scopus database