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XRD Analysis and Modeling of Na-Montmorillonite Interkalated with Octadecylamine

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26520%2F00%3A63500003" target="_blank" >RIV/00216305:26520/00:63500003 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    XRD Analysis and Modeling of Na-Montmorillonite Interkalated with Octadecylamine

  • Original language description

    Natural Na-montmorillonite (product of Southern Clay Product, Inc.) with the formula (Na 0,67 K 0,01 Ca 0,02)0,70 (Al 2,90 Mg 0,59 Fe 0,49 Ti 0,01)3,99 Si 7,92 Al 0,08)8 O 20 (OH) 4 was satureted with various amount of octadecylamine (NH2C18H37). The basal spacings d(00l) of natural Na-MMT and intercalated Na-MMt with the octadecylamine (ODA) were determined by X-ray powder diffraction (XRD) procedure. Theoretical XRD patterns of intercalated products were calculated using computer profile modeling program PROFA. The calculated set of basal diffraction for ODA molecules packed in Na-MMT as monolayer with d(001)=3,3 nm, d(002)=1,7 nm and d(003)=1,1 nm and as bilayer with d(001)=5,4 nm, d(002)=2,7 nm, d(003)=1,8 nm, d(004)=1,4 nm, d(005)=1,1nm were compared with observed data. The molecular modeling were used to present the detailed three-dimensional bilayer ODA/Na-MMT structure.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CD - Macromolecular chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2000

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Book of Abstracts, XVIth Conference on Clay Mineralogy and Petrology

  • ISBN

  • ISSN

  • e-ISSN

  • Number of pages

    1

  • Pages from-to

  • Publisher name

    ed. M. Šťastný

  • Place of publication

    Karlovy Vary

  • Event location

  • Event date

  • Type of event by nationality

  • UT code for WoS article