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Self-Propelled Multifunctional Microrobots Harboring Chiral Supramolecular Selectors for "Enantiorecogniton-on-the-Fly"

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F22%3APU145109" target="_blank" >RIV/00216305:26620/22:PU145109 - isvavai.cz</a>

  • Result on the web

    <a href="https://onlinelibrary.wiley.com/doi/10.1002/anie.202116090" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1002/anie.202116090</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/anie.202116090" target="_blank" >10.1002/anie.202116090</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Self-Propelled Multifunctional Microrobots Harboring Chiral Supramolecular Selectors for "Enantiorecogniton-on-the-Fly"

  • Original language description

    Herein, a general procedure for the synthesis of multifunctional MRs, which simultaneously exhibit i) chiral, ii) magnetic, and iii) fluorescent properties in combination with iv) self-propulsion, is reported. Self-propelled Ni@Pt superparamagnetic microrockets have been functionalized with fluorescent CdS quantum dots carrying a chiral host biomolecule as beta-cyclodextrin (beta-CD). The "on-the-fly" chiral recognition potential of MRs has been interrogated by taking advantage of the beta-CD affinity to supramolecularly accommodate different chiral biomolecules (i.e., amino acids). As a proof-of-concept, tryptophan enantiomers have been discriminated with a dual-mode (optical and electrochemical) readout. This approach paves the way to devise intelligent cargo micromachines with "built-in" chiral supramolecular recognition capabilities to elucidate the concept of "enantiorecognition-on-the-fly", which might be facilely customized by tailoring the supramolecular host-guest encapsulation.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2022

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

  • ISSN

    1433-7851

  • e-ISSN

    1521-3773

  • Volume of the periodical

    61

  • Issue of the periodical within the volume

    14

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    7

  • Pages from-to

    1-7

  • UT code for WoS article

    000752944600001

  • EID of the result in the Scopus database

    2-s2.0-85124569445