Self-Propelled Multifunctional Microrobots Harboring Chiral Supramolecular Selectors for "Enantiorecogniton-on-the-Fly"
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F22%3APU145109" target="_blank" >RIV/00216305:26620/22:PU145109 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/10.1002/anie.202116090" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1002/anie.202116090</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.202116090" target="_blank" >10.1002/anie.202116090</a>
Alternative languages
Result language
angličtina
Original language name
Self-Propelled Multifunctional Microrobots Harboring Chiral Supramolecular Selectors for "Enantiorecogniton-on-the-Fly"
Original language description
Herein, a general procedure for the synthesis of multifunctional MRs, which simultaneously exhibit i) chiral, ii) magnetic, and iii) fluorescent properties in combination with iv) self-propulsion, is reported. Self-propelled Ni@Pt superparamagnetic microrockets have been functionalized with fluorescent CdS quantum dots carrying a chiral host biomolecule as beta-cyclodextrin (beta-CD). The "on-the-fly" chiral recognition potential of MRs has been interrogated by taking advantage of the beta-CD affinity to supramolecularly accommodate different chiral biomolecules (i.e., amino acids). As a proof-of-concept, tryptophan enantiomers have been discriminated with a dual-mode (optical and electrochemical) readout. This approach paves the way to devise intelligent cargo micromachines with "built-in" chiral supramolecular recognition capabilities to elucidate the concept of "enantiorecognition-on-the-fly", which might be facilely customized by tailoring the supramolecular host-guest encapsulation.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN
1433-7851
e-ISSN
1521-3773
Volume of the periodical
61
Issue of the periodical within the volume
14
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
1-7
UT code for WoS article
000752944600001
EID of the result in the Scopus database
2-s2.0-85124569445