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Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F22%3APU147074" target="_blank" >RIV/00216305:26620/22:PU147074 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216224:14310/22:00128051 RIV/61989100:27240/22:10250670

  • Result on the web

    <a href="https://onlinelibrary.wiley.com/doi/10.1002/adma.202206382" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1002/adma.202206382</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/adma.202206382" target="_blank" >10.1002/adma.202206382</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry

  • Original language description

    Succeeding graphene, 2D inorganic materials made of reactive van der Waals layers, like 2D germanane (2D-Ge) derivatives, have attracted great attention because their physicochemical characteristics can be entirely tuned by modulating the nature of the surface substituent. Although very interesting from a scientific point of view, almost all the reported works involving 2D-Ge derivatives are focused on computational studies. Herein, a first prototype of organic-inorganic 2D-Ge heterostructure has been synthesized by covalently anchoring thiol-rich carbon dots (CD-SH) onto 2D allyl germanane (2D-aGe) via a simple and green "one-pot" click chemistry approach. Remarkably, the implanted characteristics of the carbon nanomaterial provide new physicochemical features to the resulting 0D/2D heterostructure, making possible its implementation in yet unexplored optoelectronic tasks-e.g., as a fluorescence resonance energy transfer (FRET) sensing system triggered by supramolecular pi-pi interactions-that are inaccessible for the pristine 2D-aGe counterpart. Consequently, this work builds a foundation toward the robust achievement of functional organic-inorganic 2D-Ge nanoarchitectonics through covalently assembling thiol-rich carbon nanoallotropes on commercially available 2D-aGe.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2022

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ADVANCED MATERIALS

  • ISSN

    0935-9648

  • e-ISSN

    1521-4095

  • Volume of the periodical

    34

  • Issue of the periodical within the volume

    45

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    8

  • Pages from-to

    „“-„“

  • UT code for WoS article

    000865568200001

  • EID of the result in the Scopus database

    2-s2.0-85139391431