Weak antiferromagnetic interaction in Cu(II) complex with semi-coordination exchange pathway

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F22%3APU147269" target="_blank" >RIV/00216305:26620/22:PU147269 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S027753872200314X?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S027753872200314X?via%3Dihub</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2022.115962" target="_blank" >10.1016/j.poly.2022.115962</a>

Result language
angličtina
Original language name
Weak antiferromagnetic interaction in Cu(II) complex with semi-coordination exchange pathway
Original language description
We present structural and magnetic studies of complex [Cu(dpt)(NCS)2], 1a, dpt = bis(3-aminopropyl)amine. A weak antiferromagnetic interaction mediated by a CuMIDLINE HORIZONTAL ELLIPSIS 7C non-covalent interaction was identified by magnetometry measurements, and the exchange magnitude (J = -2.24 cm-1, J stands for isotropic magnetic exchange constant) was determined. These results were supported by theoretical calculations (DFT) and the nature of the CuMIDLINE HORIZONTAL ELLIPSIS 7C interaction was studied by QT-AIM. It was confirmed that the CuMIDLINE HORIZONTAL ELLIPSIS 7C non-covalent interaction could be described as semi-coordination. The obtained results were compared to those previously reported for the isomorphous complex [Co(dpt)(NCS)2].
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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